Room temperature fluorination of 1,3-diketones and enol acetates with xenon difluoride

Authors:
  • BZBarbara Zajc
    Barbara Zajc
  • MZMarko Zupan
    Marko Zupan
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Abstract
Fluorination of 1,3-diketones with xenon difluoride in the presence of the insoluble cross-linked polystyrene–4-vinylpyridine complex with boron trifluoride and insoluble cross-linked polystyrene–4-vinyl-pyridine resins resulted in the formation of mono- and di-fluoro products, while reactions with enol acetates in the presence of hydrogen fluoride gave α-fluoroketones.