Landscape equivalent of the shoving model
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Abstract
It is shown that the shoving model expression for the average relaxation time of viscous liquids follows largely from a classical "landscape" estimation of barrier heights from curvature at energy minima. The activation energy involves both instantaneous bulk and shear moduli, but the bulk modulus contributes less than 8% to the temperature dependence of the activation energy. This reflects the fact that the physics of the two models are closely related.Keywords
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This publication has 1 reference indexed in Scilit:
- Theory of relaxation in viscous liquids and glassesThe Journal of Chemical Physics, 1984