On the Role of the Nature of Cerium-Containing Compounds in the Plasma Synthesis of Luminescent Materials

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Abstract
A plasma-chemical process resulting from a microwave discharge initiated in metal–dielectric powder mixtures was used to produce luminescent materials based on Al5O6N doped with Ce3+ ions. The self-non-selfsustained discharge was initiated by microwave radiation pulses with a frequency of 75 GHz, power of 400 kW, and duration of 8 ms in Al/γ-Al2O3/melamine powder mixtures, cerium was introduced in the form of CeO2 and Ce(acac)3·H2O, and by preliminary doping of γ-Al2O3 with Ce3+ ions. Kinetic parameters of the plasma-chemical process were determined, microscopic and X-ray diffraction analyses of the products were conducted, and pulsed cathodoluminescence spectra were recorded. It was shown that the rate of the plasma-chemical process and the efficiency of Ce3+ ions introduction into the produced Al5O6N aluminum oxynitride phase are determined to a large extent by the form of cerium present in the reaction mixture.

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