A Cyclic Hexairon(III) Complex with an Octahedrally Coordinated Sodium Ion at the Center, an Example of the [12]Metallacrown‐6 Structure Type
- 7 March 1995
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 34 (4) , 467-469
Abstract
A crown composed purely of inorganic components forms the core of complex cation 1. Interest in this polyiron ion is based on its potential relevance to intermediates in the formation of the ferritin core and the hydrolytic polymerization of FeIII salts. The crown structure is supported by the inclusion of a sodium ion within the Fe6O6 ring. equation imageKeywords
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