Transition from ZIF-L-Co to ZIF-67: a new insight into the structural evolution of zeolitic imidazolate frameworks (ZIFs) in aqueous systems
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- 25 September 2015
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 17 (43) , 8212-8215
Abstract
A leaf-like ZIF-L-Co is synthesized for the first time and the molar ratio of Hmim/Co plays an important role in the synthesis. ZIF-L-Co is a transient phase at the initial stage of ZIF-67 crystal growth. The crystallization process of ZIF-67 from ZIF-L-Co follows a solid transformation mechanism.Keywords
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