Chain “stationary” insertion mechanism and production of isotactic polypropylene with C 1 symmetric catalyst systems
Authors:
- 1 March 2006
- journal article
- Published by Pleiades Publishing Ltd in Kinetics and Catalysis
- Vol. 47 (2) , 257-267
Abstract
In this contribution, the stereochemistry of propylene insertion/propagation reactions with a variety of C1symmetric metallocene catalysts, containing bridged cyclopentadienyl-fluorenyl ligand for...Keywords
This publication has 61 references indexed in Scilit:
- Syndiotactic Poly(propylene) from [Me2Si(3,6‐di‐tert‐butyl‐9‐fluorenyl)(N‐tert‐butyl)]TiCl2–Based Catalysts: Chain‐End or Enantiotopic‐Sites Stereocontrol?Macromolecular Chemistry and Physics, 2003
- Amine Elimination Reactions between Homoleptic Silylamide Lanthanide Complexes and an Isopropylidene-Bridged Cyclopentadiene−Fluorene SystemOrganometallics, 2002
- Ultrahigh Molecular Weight Polypropene Elastomers by High Activity “Dual-Side” Hafnocene CatalystsMacromolecules, 2002
- Theoretical and Spectroscopic UV Study of the EtInd2ZrCl2/MAO, EtInd2ZrCl2/MAO-AlCl3 and EtInd2ZrCl2/MAO-Ethyl Benzoate InteractionMacromolecular Chemistry and Physics, 2001
- A Density Functional Theory (DFT) Quantum-Chemical Approach to the Real Structure of Poly(methylaluminoxane)Macromolecular Theory and Simulations, 2001
- Highly Electrophilic Olefin Polymerization Catalysts. Counteranion and Solvent Effects on Constrained Geometry Catalyst Ion Pair Structure and ReactivityJournal of the American Chemical Society, 1998
- Influence of π-Ligand Substitutions on the Regiospecificity and Stereospecificity in Isospecific Zirconocenes for Propene Polymerization. A Molecular Mechanics AnalysisMacromolecules, 1998
- Molecular mechanics study of zirconocenium catalyzed isospecific polymerization of propyleneJournal of Polymer Science Part A: Polymer Chemistry, 1995
- Theoretical Studies of Ziegler-Natta Catalysis: Structural Variations and Tacticity ControlJournal of the American Chemical Society, 1994
- Hemitactic polymersMacromolecules, 1985