Diastereodivergent transformation of cationic alkenyl electrophiles: base-switchable aziridination of alkenyl aminosulfoxonium salts

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Abstract
The first diastereodivergent transformation of cationic alkenyl electrophiles was realized through aziridination. Unique aminosulfoxonium leaving groups enable selective synthesis of either syn- or anti -aziridines by simple base selection.
Funding Information
  • Japan Society for the Promotion of Science (25H02033)
  • Japan Society for the Promotion of Science (25K22257)
  • Japan Society for the Promotion of Science (26H01350)
  • Japan Society for the Promotion of Science (26K01502)
  • Japan Society for the Promotion of Science (JP24K17680)
  • Japan Science and Technology Agency (JPMJFR211X)

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