Palladium‐Catalyzed Enantioselective C-H Arylation for the Synthesis of P‐Stereogenic Compounds
Authors:
- 2 April 2015
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 54 (21) , 6265-6269
Abstract
A palladium‐catalyzed enantioselective CH arylation of N‐(o‐bromoaryl)‐diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P‐stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P‐chiral biphenyl monophosphine ligands.Keywords
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