A metal–organic framework with coordinatively unsaturated metal centers and microporous structure
- 10 June 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 12 (8) , 2347-2349
Abstract
A novel two dimensional porous framework [Cd3(BTB)2(DEF)4]n·2nDEF (1) based on {Cd3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits promising adsorption for N2 after activation to obtain coordinatively unsaturated Cd centers, and SEM characterization demonstrates interesting microporous structure inside of the compound.Keywords
This publication has 24 references indexed in Scilit:
- Gas Adsorption Study on Mesoporous Metal−Organic Framework UMCM-1The Journal of Physical Chemistry C, 2010
- Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clustersChemical Communications, 2008
- A 3D Porous Cobalt−Organic Framework Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop TransitionInorganic Chemistry, 2007
- A Dynamic Porous Magnet Exhibiting Reversible Guest‐Induced Magnetic Behavior ModulationAdvanced Materials, 2007
- Three-Dimensional Porous Coordination Polymer Functionalized with Amide Groups Based on Tridentate Ligand: Selective Sorption and CatalysisJournal of the American Chemical Society, 2007
- A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of PolyoxometalateJournal of the American Chemical Society, 2005
- Synthesis, X‐ray Crystal Structures, and Gas Sorption Properties of Pillared Square Grid Nets Based on Paddle‐Wheel Motifs: Implications for Hydrogen Storage in Porous MaterialsChemistry – A European Journal, 2005
- Porous Lanthanide-Organic Frameworks: Synthesis, Characterization, and Unprecedented Gas Adsorption PropertiesJournal of the American Chemical Society, 2003
- Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageScience, 2002
- Rational Synthesis of Stable Channel-Like Cavities with Methane Gas Adsorption Properties: [{Cu2(pzdc)2(L)}n] (pzdc=pyrazine-2,3-dicarboxylate; L=a Pillar Ligand)Angewandte Chemie International Edition, 1999