Neutral organocopper(iii) complexes
- 22 January 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1176-1177
Abstract
Neutral organocopper(III) complexes have been prepared from organocuprate(I) reagents and alkyl halides in the presence of certain strongly electron donating ligands.Keywords
This publication has 9 references indexed in Scilit:
- Organocuprate Cross‐Coupling: The Central Role of the Copper(III) Intermediate and the Importance of the Copper(I) PrecursorAngewandte Chemie International Edition, 2007
- NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman CupratesJournal of the American Chemical Society, 2007
- Organocuprate Conjugate Addition: The Square-Planar “CuIII” IntermediateJournal of the American Chemical Society, 2007
- Rapid Injection NMR in Mechanistic Organocopper Chemistry. Preparation of the Elusive Copper(III) IntermediateJournal of the American Chemical Society, 2007
- Opening the ‘black box’: oscillations in organocuprate conjugate addition reactionsChemical Communications, 2005
- Rapid-Injection NMR Study of Iodo- and Cyano-Gilman Reagents with 2-Cyclohexenone: Observation of π-Complexes and Their Rates of FormationJournal of the American Chemical Society, 2002
- It's on lithium! an answer to the recent communication which asked the question: ‘if the cyano ligand is not on copper, then where is it?’Chemical Communications, 1996
- New copper chemistry. 20. Lithium cyanocuprates, RCu(CN)Li: first observation of two-bond carbon-13-carbon-13 NMR couplings in organocupratesJournal of the American Chemical Society, 1991
- The composition of lithium methylcuprates in ether solventsJournal of the American Chemical Society, 1977