Hydrogen and proton exchange at carbon. Imbalanced transition state and mechanism crossover
Open Access
- 29 November 2019
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 11 (4) , 1006-1010
Abstract
Using the remarkable study of C–H oxidation of substituted fluorenyl-benzoates as an example, we have shown that a mechanism crossover takes place upon decreasing the driving force, from a CPET pathway to a PTET pathway.Keywords
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