Enantioselective Allylation of Aldehydes Using Tartrate Ester Modified Allylsilanes
Authors:
- 1 February 1997
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 26 (2) , 129-130
Abstract
Tartrate-ester modified allylsilanes, 2-allyl-1,3,2-dioxasilolane-4,5-dicarboxylic esters, (1), were found to serve as useful reagents for regiospecific and stereoselecive allylation of aldehydes. Reactions of 1 with achiral aldehydes without any catalyst gave the corresponding homoallyl alcohols in good yields (70-90%) with the ee values up to 80%.Keywords
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