Work distribution for the adiabatic compression of a dilute and interacting classical gas
- 20 February 2007
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 75 (2) , 021116
Abstract
We consider a simple, physically motivated model of a dilute classical gas of interacting particles, initially equilibrated with a heat bath, undergoing adiabatic and quasistatic compression or expansion. This provides an example of a thermodynamic process for which non-Gaussian work fluctuations can be computed exactly from microscopic principles. We find that the work performed during this process is described statistically by a gamma distribution, and we use this result to show that the model satisfies the nonequilibrium work and fluctuation theorems, but not a prediction based on linear response theory.Keywords
All Related Versions
This publication has 25 references indexed in Scilit:
- Fluctuation theorem for the effusion of an ideal gasPhysical Review E, 2006
- Rare events and the convergence of exponentially averaged work valuesPhysical Review E, 2006
- Ordering of limits in the Jarzynski equalityThe Journal of Chemical Physics, 2006
- Biased Sampling of Nonequilibrium Trajectories: Can Fast Switching Simulations Outperform Conventional Free Energy Calculation Methods?The Journal of Physical Chemistry B, 2005
- Dissipated work in driven harmonic diffusive systems: General solution and application to stretching Rouse polymersThe European Physical Journal B, 2005
- Work probability distribution in single-molecule experimentsEurophysics Letters, 2005
- Practical Applicability of the Jarzynski Relation in Statistical Mechanics: A Pedagogical ExampleThe Journal of Physical Chemistry B, 2005
- Direct dynamical calculation of entropy and free energy by adiabatic switchingPhysical Review Letters, 1990
- Über die mechanischen Grundlagen der ThermodynamikAnnalen der Physik, 1910
- Über die mechanischen Grundlagen der ThermodynamikAnnalen der Physik, 1910