Water-soluble iridium and rhodium complexes with tris(hydroxymethyl)phosphine and their catalysis in biphasic hydrogenation and hydroformylation

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Abstract
Novel water-soluble Ir and Rh complexes with tris(hydroxymethyl)phosphine catalyse the selective hydrogenation of the CO bond of cinnamaldehyde and the hydroformylation of pent-1-ene both under biphasic conditions.