Closed-loop hydrostannylation of white phosphorus using Bu 3 SnCl and NaBH 4 : one-pot access to organophosphorus compounds

Authors:
Open Access
Publisher website
Google Scholar
Abstract
Organophosphorus compounds are synthesized directly from white phosphorus using Bu 3 SnCl, NaBH 4 and organic electrophiles (E + ). Recycling of the tin reagent is demonstrated in the synthesis of tetrakis(hydroxymethyl)phosphonium chloride (THPC).
Funding Information
  • Deutsche Forschungsgemeinschaft (WO 1496/12-1)
  • Engineering and Physical Sciences Research Council (EP/V056069/1)
  • Alexander von Humboldt-Stiftung

This publication has 30 references indexed in Scilit: