Homochiral Zn and Cd Coordination Polymers Containing Amino Acid−Tetrazole Ligands
- 1 November 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (24) , 7710-7712
Abstract
The reactions of (S)-3-cyanophenylalanine with NaN3 in the presence of H2O and Lewis acids (ZnCl2 and CdCl2) afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two compounds are isostructural with noninterpenetrated SrAl2 topology. The structure of these coordination polymers gives new insight into Sharpless' reaction of chiral 5-substituted 1H-tetrazole and homochiral supramolecular array constructions.Keywords
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