Unlocking spontaneous chiral resolution in silver clusters through steric and anionic control

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Abstract
Spontaneous chiral resolution was achieved in C 3 -symmetric trinuclear silver clusters by tuning ligand steric effects and anions. Anion exchange reversibly switches homochiral and racemic polymorphs, enabling control of spontaneous resolution.
Funding Information
  • National Natural Science Foundation of China (92261109)
  • National Natural Science Foundation of China (22371280)
  • Natural Science Foundation of Fujian Province (2023J01219)
  • State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University (202426)
  • Chinese Academy of Sciences (CXZX-2022-GH02)
  • Natural Science Foundation of Xiamen Municipality (3502Z202371030)

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