1,3-Dipolar Cycloaddition of 1-Methyl-3-oxidopyridinium and Sulfonylethenes. A Synthesis of 2-Tropanols and Monofluorinated 2-Tropanol
Authors:
- 1 April 1989
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (4) , 593-596
Abstract
2α- and 2β-Tropanols were synthesized by 1,3-dipolar cycloaddition of phenyl vinyl sulfone and 1-methyl-3-oxidopyridinium regio- and stereoselectively. The method was extended to a preparation of 6α-fiuoro-2β-tropanol from 1-(benzenesulfonyl)-1-fluoroethene.Keywords
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