Nucleophilic addition of aromatic amide oximes to [2-B10H9NCC2H5]– anion
- 1 January 2017
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of General Chemistry
- Vol. 87 (1) , 37-43
Abstract
A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.Keywords
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