Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets
Open Access
- 3 September 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 42 (45) , 15931-15936
Abstract
A solution-based two-dimensional interfacial reaction between 5,10,15,20-tetra(4-pyridyl)-porphinato zinc(II) (ZnTPyP, 1) and Cu(NO3)2·3H2O, 2, results in the assembly of uniform preferentially oriented highly crystalline metal–organic framework nanosheets, NAFS-21 that have sub-micron planar size and mono-molecular thickness.Keywords
This publication has 35 references indexed in Scilit:
- Step-by-Step Fabrication of a Highly Oriented Crystalline Three-Dimensional Pillared-Layer-Type Metal–Organic Framework Thin Film Confirmed by Synchrotron X-ray DiffractionJournal of the American Chemical Society, 2012
- Patterning Techniques for Metal Organic FrameworksAdvanced Materials, 2012
- Introduction to Metal–Organic FrameworksChemical Reviews, 2012
- Surface Chemistry of Metal–Organic Frameworks at the Liquid–Solid InterfaceAngewandte Chemie International Edition, 2010
- Hybrid porous solids: past, present, futureChemical Society Reviews, 2007
- Oriented Growth of the Metal Organic Framework Cu3(BTC)2(H2O)3·xH2O Tunable with Functionalized Self-Assembled MonolayersJournal of the American Chemical Society, 2007
- Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111)Journal of the American Chemical Society, 2005
- Functional Porous Coordination PolymersAngewandte Chemie International Edition, 2004
- Enhancement of Molecular Properties in Thin Films by Controlled Orientation of Molecular Building BlocksJournal of the American Chemical Society, 2004
- Growth and characterization of metal(II) alkanebisphosphonate multilayer thin films on gold surfacesJournal of the American Chemical Society, 1993