Engineering macrocyclic high performance pentagonal bipyramidal Dy( iii ) single-ion magnets
Open Access
- 3 September 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 56 (80) , 12037-12040
Abstract
We highlight the vast synthetic scope for macrocyclic engineering of magnetic anisotropy, generating a high performance pentagonal bipyramidal Dy( iii ) single-ion magnet where the weak equatorial ligand field is created entirely by using a macrocycle.Keywords
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Funding Information
- Anusandhan National Research Foundation (CRG/2018/000430)
- Anusandhan National Research Foundation (DST/SJF/CSA03/2018-10)
- Anusandhan National Research Foundation (SB/SJF/2019-20/12)
- Engineering and Physical Sciences Research Council (EP/M000923/1)
- Engineering and Physical Sciences Research Council (EP/N01331X/1)
This publication has 56 references indexed in Scilit:
- Switching the anisotropy barrier of a single-ion magnet by symmetry change from quasi-D5h to quasi-OhChemical Science, 2013
- Interplay of Strongly Anisotropic Metal Ions in Magnetic Blocking of ComplexesInorganic Chemistry, 2013
- A Record Anisotropy Barrier for a Single-Molecule MagnetJournal of the American Chemical Society, 2007
- Local properties of quantum chemical systems: The LoProp approachThe Journal of Chemical Physics, 2004
- Shape and Symmetry of Heptacoordinate Transition‐Metal Complexes: Structural TrendsChemistry – A European Journal, 2003
- Distorted MnIVMnIII3 Cubane Complexes as Single-Molecule MagnetsJournal of the American Chemical Society, 1996
- High-spin molecules: [Mn12O12(O2CR)16(H2O)4]Journal of the American Chemical Society, 1993
- Theory of Spin–Lattice RelaxationPhysica Status Solidi (b), 1983
- Optical‐acoustic two‐phonon relaxation in spin systemsPhysica Status Solidi (b), 1979
- Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)Journal of the Chemical Society, Chemical Communications, 1977