NiS 2 nanosheet arrays on stainless steel foil as binder‐free anode for high‐power sodium‐ion batteries

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Abstract
Owing to the wide range and low cost of sodium resources, sodium‐ion batteries (SIBs) have received extensive attention and research. Metal sulfides with high theoretical capacity are used as promising anode materials for SIBs. This paper presents the electrochemical performance of the binder‐free NiS 2 nanosheet arrays grown on stainless steel (SS) substrate (NiS 2 /SS) using an in situ growth and sulfidation strategy as anode for sodium ion batteries. Owing to the close connection between the NiS 2 nanosheet arrays and the SS current collector, the NiS 2 /SS anode demonstrates high rate capability with a reversible capacity of 492.5 mAh·g −1 at 5.0C rate. Such rate capability is superior to that of NiS 2 nanoparticles (NiS 2 /CMC: 41.7 mAh·g −1 at 5.0C, NiS 2 /PVDF: 7.3 mAh·g −1 at 5.0C) and other Ni sulfides (100–450 mAh·g −1 at 5.0C) reported. Furthermore, the initial reversible specific capacity and Coulombic efficiency of NiS 2 /SS are 786.5 mAh·g −1 and 81%, respectively, demonstrating a better sodium storage ability than those of most NiS 2 anodes reported for SIBs. In addition, the amorphization and conversion mechanism during the sodiation/desodiation process of NiS 2 are proposed after investigation by in situ X‐ray diffraction (XRD) measurements of intermediate products at successive charge/discharge stages.
Funding Information
  • National Natural Science Foundation of China (NNSFC)
  • National Natural Science Foundation of China (21673051)
  • Guangdong Provincial Department of Science and Technology (2019A050510043)
  • National Natural Science Foundation of China (NNSFC)
  • National Natural Science Foundation of China (21673051)
  • Guangdong Provincial Department of Science and Technology (2019A050510043)
  • Department of Science and Technology of Zhuhai City (ZH22017001200059PWC)

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