Polymer Brush and Inorganic Oxide Hybrid Nanodielectrics for High Performance Organic Transistors
Authors:
- 7 April 2010
- journal article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry B
- Vol. 114 (16) , 5315-5319
Abstract
A novel covalence-linked PMMA-SiO(2) hybrid nanodielectrics was prepared by grafting approximately 10 nm PMMA brush onto the SiO(2) (approximately 9 nm) surface, which effectively combines the respective merits of PMMA and SiO(2). As a result, the hybrid nanodielectrics exhibit excellent dielectric performance (e.g., low leakage density (<10(-7) A/cm(2) at 6 MV/cm), high breakdown voltage (7 MV/cm), high capacitance (142 nF/cm(2)), good operational stability, and good compatibility with organic semiconductors), and enable organic field-effect transistors (OFETs) to work with high performance and low voltage. These results may open a way to build ultrathin dielectrics for high performance transistor and circuit, as well as for microelectronics, nanoelectronics, and organic electronics.Keywords
This publication has 44 references indexed in Scilit:
- Optimizing molecular orientation for high performance organic thin film transistors based on titanyl phthalocyanineJournal of Materials Chemistry, 2009
- Crystalline Ultrasmooth Self-Assembled Monolayers of Alkylsilanes for Organic Field-Effect TransistorsJournal of the American Chemical Society, 2009
- High‐Performance Thin‐Film Transistors from Solution‐Processed Cadmium Selenide and a Self‐Assembled Multilayer Gate DielectricAdvanced Materials, 2008
- Flexible Inorganic/Organic Hybrid Thin‐Film Transistors Using All‐Transparent Component MaterialsAdvanced Materials, 2007
- Bilayer Organic–Inorganic Gate Dielectrics for High‐Performance, Low‐Voltage, Single‐Walled Carbon Nanotube Thin‐Film Transistors, Complementary Logic Gates, and p–n Diodes on Plastic SubstratesAdvanced Functional Materials, 2006
- Low-voltage polymer thin-film transistors with a self-assembled monolayer as the gate dielectricApplied Physics Letters, 2005
- Gate Dielectrics for Organic Field‐Effect Transistors: New Opportunities for Organic ElectronicsAdvanced Materials, 2005
- Low-voltage organic transistors with an amorphous molecular gate dielectricNature, 2004
- Controlled Grafting of Well-Defined Polymers on Hydrogen-Terminated Silicon Substrates by Surface-Initiated Atom Transfer Radical PolymerizationThe Journal of Physical Chemistry B, 2003
- Low‐k Insulators as the Choice of Dielectrics in Organic Field‐Effect TransistorsAdvanced Functional Materials, 2003