Sunflower oil-based polyurethane/graphene composite: Synthesis and properties

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Abstract
Polyurethane/graphene composites have attracted significant attention featuring their wide applications in automotive interiors, coatings, and leather parts to bioengineering. This research focuses on the facile synthesis of biobased polyurethane (PU) by employing sunflower oil as a renewable resource. The synthesized biobased PU was reinforced with graphene nanoplatelets (GNP) and graphene nanoribbons (GNR) to fabricate composite films by solution-casting technique. By changing the filler content (0.01-0.05 wt%), a series of composite films were prepared. The addition of graphene derivatives to the PU matrix improved the mechanical, thermal, and surface properties of the composites compared to the pristine PU film. The incorporation of GNR and GNP fillers enhanced the storage modulus of polymeric film, as for neat PU, was noted maximum at 892 MPa which increased and noticed a maximum of 1121 MPa and 1487 MPa for 0.02 wt % GNP/PU and GNR/PU composite films, respectively. The tensile strength was obtained at 35 MPa and 14 MPa for 0.02 wt % GNP/PU and 0.01 wt % GNR/PU, as compared to 9.45 MPa for the pure PU film. The morphological studies by atomic force microscopy showed a good distribution of GNR and GNP fillers within the polyurethane matrix. The GNP/PU and GNR/PU composite films displayed excellent chemical resistance to different solvents. This work put forward a great utilization of renewable sunflower oil and graphene derivatives to fabricate PU composites with improved properties for potential applications.

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