Electrocoagulation for the Treatment of Metals Machining Plants Effluents: Experimental and Modeling Study
Authors:
- 21 April 2023
- journal article
- research article
- Published by Wiley in Chemical Engineering & Technology
- Vol. 46 (7) , 1521-1532
Abstract
Treatment of effluents discharged from mechanical machining of copper and copper alloys for removal of cutting oils and toxic copper ions by electrocoagulation was studied using a cell containing two steel electrodes and a built‐in heat transfer facility. Current density, initial pH of the solution, temperature, starting pollutants' concentrations, amount of NaCl supportive electrolyte, and the impact of gas sparging were investigated. Response surface methodology was used to correlate % oil removal, % copper removal, and electrical energy consumption to the affecting variables. The results imply that the cubic model fits well with the experimental results. The electrocoagulation of oil and copper from waste solutions was optimized using the response optimizer. The simultaneous removal of oil and Cu2+ in the same cell could lower the operational and capital expenses of wastewater treatment.Keywords
This publication has 18 references indexed in Scilit:
- Production of copper powder from wastewater containing CuSO4 and alcoholic additives in a modified stirred tank reactor by cementationHydrometallurgy, 2011
- Performance of an electrocoagulation cell with horizontally oriented electrodes in oil separation compared to a cell with vertical electrodesChemical Engineering Journal, 2009
- Intensification of Rate of Diffusion Controlled Reactions in a Parallel Plate Electrochemical Reactor Stirred by a Curtain of Electrochemically Generated Gas BubblesChemical Engineering & Technology, 2007
- Hydrodynamic Effects on the Performance of Electro-coagulation/Electro-flotation for the Removal of Dyes from Textile WastewaterIndustrial & Engineering Chemistry Research, 2005
- Fundamentals, present and future perspectives of electrocoagulationJournal of Hazardous Materials, 2004
- Electrochemical technologies in wastewater treatmentSeparation and Purification Technology, 2004
- Liquid-solid mass transfer from horizontal woven screen packing in bubble column reactorsThe Canadian Journal of Chemical Engineering, 2000
- Destabilization of cutting oil emulsions using inorganic salts as coagulantsColloids and Surfaces A: Physicochemical and Engineering Aspects, 1998
- The effect of electrolytically evolved gas bubbles on the thickness of the diffusion layer—IIElectrochimica Acta, 1973
- Stofftransport bei der Elektrolyse mit GasrührungChemie Ingenieur Technik, 1971