Seven-coordinated scandium(iii) chloroions in ScCl3–CsCl molten mixtures at 600–900 °C

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Abstract
Raman spectroscopic measurements of ScCl3–CsCl molten mixtures in the temperature range of 600–900 °C and compositions up to 25 mol% ScCl3 indicate that the predominant scandium(III) chloroions in these melts are ScCl3− 6 and a novel all chloride highly coordinated ScCl4− 7.