EXCEPTIONS TO HUDSON'S RULES OF ISOROTATION: THE NUCLEAR MAGNETIC RESONANCE SPECTRA OF ANOMERIC PYRIMIDINE 2-DEOXY-D-RIBONUCLEOSIDES
Authors:
- R. U. LemieuxRLR. U. Lemieux
- M. HofferMHM. Hoffer
- 1 January 1961
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 39 (1) , 110-115
Abstract
Nuclear magnetic resonance spectroscopy and optical rotatory dispersion measurements were used to correlate the configurations of anomeric pairs for the 1-(2-deoxy-D-ribofuranosyl) derivatives of 5-methyl- and 5-fluoro-uracil. The optical rotations of the anomers were found opposite to those expected on the basis of Hudson's rules of isorotation.Keywords
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