Ultrasonic Observation of a Strong Pretransitional Anomaly near a Nematic-Smectic-APhase Transition

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Abstract
Strong anomalies in the velocity and attenuation of longitudinal ultrasound in the megahertz range were observed for the first time in the vicinity of the nematic-smectic-A phase transition in a liquid crystal (terephthal-bis-p−p′-butylaniline). Results are in strong contradiction with theoretical predictions and are qualitatively consistent with a picture involving both critical fluctuations and relaxation of the smectic order parameter, similar to that observed near the λ transition in liquid helium.

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