Synthesis and Spectroscopic Characterization of a Complex of 1, 10‐Phenanthroline with Magnesium
- 7 January 2003
- journal article
- kurze mitteilung
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 629 (1) , 12-14
Abstract
The complex [Mg(1, 10‐phenanthroline)3(NO3)2]·9H2O has been synthesized. It forms crystals having the shape of sheaves with very thin filaments. The compound has been characterized by UV, IR, NMR and mass spectra. The UV and mass spectra are indicative of an electron density transfer from NO3— to Mg2+. On the base of the spectroscopic studies a model of the crystal structure has been proposed.Keywords
This publication has 4 references indexed in Scilit:
- A Gas-Phase Study of the Coordination of Mg2+ with Oxygen- and Nitrogen-Containing LigandsJournal of the American Chemical Society, 2000
- Crystal Structure and IR Spectrum of Diaqua(o-phenanthroline) bis(saccharinato)lead(II)Zeitschrift für anorganische und allgemeine Chemie, 2000
- Hydration Energies and Entropies for Mg2+, Ca2+, Sr2+, and Ba2+ from Gas-Phase Ion−Water Molecule Equilibria DeterminationsThe Journal of Physical Chemistry A, 1998
- The nature of .pi.-.pi. interactionsJournal of the American Chemical Society, 1990