Effects of Spodumene Flotation Tailings on Mechanical Properties of Acid-Based Geopolymer Mortar

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Abstract
This study focuses on using spodumene flotation tailings (SFT) to prepare phosphoric acid-activated metakaolin geopolymer, in which the replacement of metakaolin (MK) by a high percentage (up to 75 wt.%) of tailings was achieved. The compressive strength of geopolymer mortar was significantly improved with SFT as aggregates. In addition, the mechanical properties could also be enhanced by an increased concentration of phosphoric acid (H3PO4) solution or a decreased aggregate particle size. The optimized geopolymer mortar composite was SFT:MK = 3:1, which was activated by H3PO4 solution with a concentration of 51 vol%, followed by curing at 55 °C for 24 h. On the other hand, properties of the geopolymer mortar could also be affected by the morphology of the aggregates. For example, SFT as aggregates could produce more interconnected pores compared to standard sand. The major chemical structural units of geopolymer mortar were -P-O-Al- and AlPO4, which could be spontaneously generated according to the thermodynamic calculation results. Finally, many aluminum ions and a small amount of silicon ions could be leached from the tailings under acidic conditions.
Funding Information
  • National Key Research and Development Program of China (2021YFC2900800, 51922091, 51674207, 2019YFS0453, 2022YFS0455, 2023NSFSC1978)
  • National Natural Science Foundation of China (2021YFC2900800, 51922091, 51674207, 2019YFS0453, 2022YFS0455, 2023NSFSC1978)
  • Sichuan Science and Technology Program (2021YFC2900800, 51922091, 51674207, 2019YFS0453, 2022YFS0455, 2023NSFSC1978)

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