Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology
- 11 February 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1753-1755
Abstract
A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII 3O)FeII(TA)6(H2O)3]·(ClO4)2(NO3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.Keywords
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