Cyanide Functionalization and Oxygen Vacancy Creation in Ni‐Fe Nano Petals Sprinkled with MIL‐88A Derived Metal Oxide Nano Droplets for Bifunctional Alkaline Seawater Electrolysis

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Abstract
This work investigates novel improvements in FeNi‐layered double hydroxide (LDH)/MIL‐88A heterocomposite for sustainable seawater electrolysis through a single‐step dual functionalization process. The Fe/Ni precursor weight ratio is optimized, resulting in the formation of smaller LDH petals and nano‐sized MIL‐88A metal–organic framework, which transforms into clusters of Fe2O3 nanospheres within a nitrogen‐functionalized carbon matrix over NiFe2O4 nano petals upon calcination. Furthermore, oxygen vacancies, and nitrogen functionalization are attained in a single step by employing thermal ammonia reduction, significantly improving the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) activities. Particularly the oxygen vacancy and nitrogen functionalization are found to accelerate the O─O coupling step in OER by lowering the activation barrier. Likewise, the dual functionalization promotes destabilizing the hydride intermediates in HER potentially facilitating faster proton‐coupled electron transfer. Hence, the optimized electrode achieves current densities of 200 mA cm−2 at overpotentials of 350 and 240 mV for OER and HER respectively. The chronopotentiometry stability tests confirms the electrode's durability over 200 h at 20 mA cm−2 in alkaline seawater electrolyte. The optimized electrode, composed of cost‐effective and environmentally friendly materials, demonstrates robustness in alkaline seawater electrolytes, positioning it as a strong candidate for practical and sustainable water electrolysis applications.
Funding Information
  • National Research Foundation of Korea

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