Semiquantitative studies on the correlations between the electrostatic potential of a single DyIII ion and its energy barrier in the containing-DyIII single molecule magnets
Authors:
- 13 February 2025
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 54 (12) , 5050-5060
Abstract
We reported a novel “Y”-shaped MnIII5Dy3 complex with SMM behavior, and found that the Ucal value of individual DyIII is the highest when the electrostatic potentials from two sides of its equatorial plane are completely equivalent to each other.Keywords
Funding Information
- Hubei Provincial Key Laboratory of Green Materials for Light Industry (202409A05)
- Wuhan Institute of Technology (CX2022433)
- National Natural Science Foundation of China (21201136)
This publication has 60 references indexed in Scilit:
- Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker MetallacrownAngewandte Chemie International Edition, 2020
- Control of the Spin Dynamics of Single‐Molecule Magnets by using a Quasi One‐Dimensional ArrangementAngewandte Chemie International Edition, 2018
- A Heterometallic FeII–DyIII Single‐Molecule Magnet with a Record Anisotropy BarrierAngewandte Chemie International Edition, 2014
- Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [MnIII12] WheelChemistry – A European Journal, 2014
- A {CrIII2DyIII2} Single‐Molecule Magnet: Enhancing the Blocking Temperature through 3d Magnetic ExchangeAngewandte Chemie International Edition, 2013
- Single Pyramid Magnets: Dy5 Pyramids with Slow Magnetic Relaxation to 40 KAngewandte Chemie International Edition, 2011
- An Octanuclear [CrIII4DyIII4] 3d–4f Single‐Molecule MagnetAngewandte Chemie International Edition, 2010
- The Origin of Nonmagnetic Kramers Doublets in the Ground State of Dysprosium Triangles: Evidence for a Toroidal Magnetic MomentAngewandte Chemie International Edition, 2008
- Heterometallic [Mn5‐Ln4] Single‐Molecule Magnets with High Anisotropy BarriersChemistry – A European Journal, 2008
- Broken symmetry approach to calculation of exchange coupling constants for homobinuclear and heterobinuclear transition metal complexesJournal of Computational Chemistry, 1999