Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights
- 5 October 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 43,p. 4509-4511
Abstract
Alkoxy-amino-bis(phenolate) yttrium amide and alkoxide complexes promote the ring-opening polymerization of (3S,6S)-dimethyl-2,5-morpholinedione at 60–100 °C via a coordination–insertion polymerization mechanism.Keywords
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