Fabrication of Conductive Silver Microtubes Using Natural Catkin as a Template

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Abstract
Catkin, a natural hollow fiber, is used as a template to fabricate light, flexible, and electrically conductive silver microtubes with a high aspect ratio. The template is functionalized with tannic acid (TA)–Fe coordination complexes. Because of the metal ion chelating ability and reducibility of TA, silver nanoparticles (Ag NPs) can be formed in situ on the fiber’s surface. The as-formed Ag NPs can act as nucleation sites in subsequent electroless silver plating, leading to the formation of a compact and uniform silver coating on the microtube. The coating is constructed by densely packed Ag NPs of only 15 ± 5 nm in diameter. Because of the tight accumulation and small size of the Ag NPs, the resulting silver-coated microtubes, without any post-treatment, show an electrical resistivity of 1500 mΩ·cm at a bulk density of 0.6 g·cm–3. We find that the in situ formed nucleation sites and the stirring speed in the electroless plating play important roles in the formation of a silver coating with a high electrical conductivity. This method may be extended to fabricate conductive nanocoatings on other substrates.
Funding Information
  • National Natural Science Foundation of China (21421061, 51522308)

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