Cyclic Alternating Ring-Opening Metathesis Polymerization (CAROMP). Rapid Access to Functionalized Cyclic Polymers
- 4 August 2010
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 12 (17) , 3729-3731
Abstract
Catalysis of alternating ROMP with (H2IMes)Cl2Ru═CHPh(OiPr), the second generation Hoveyda−Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.Keywords
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