Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes
Authors:
- 1 October 2001
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 30 (10) , 976-977
Abstract
A new MOP ligand containing n-octyl group at 6 and 6′ positions of (R)-2-(diphenylphosphino)-2′-aryl-1,1′-binaphthyl skeleton was prepared and used for palladium-catalyzed asymmetric hydrosilylation of cyclic 1,3-dienes with trichlorosilane. By introduction of the n-octyl group, the palladium-phosphine catalyst became soluble in the reaction system, realizing high catalytic activity at a low reaction temperature.Keywords
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