Extraction of Lanthanides with Diamides of Dipicolinic Acid from Nitric Acid Solutions. I
- 18 July 2008
- journal article
- research article
- Published by Taylor & Francis in Separation Science and Technology
- Vol. 43 (9-10) , 2606-2618
Abstract
Three ortho-, meta-, and para-derivates of ethyl(tolyl)diamides of dipicolinic acid were synthesized and tested on their extraction performance from nitric acids solutions. Extraction of americium and lanthanides (Ln) by these compounds as a function of nitric acid concentration was studied. Distribution ratios of studied metals were determined using ICP-OES method and radiotracer 241Am. Am/Ln separation differs among studied diamides, and the best separation was found for N,N′-diethyl-N,N′-di(ortho)tolyl-diamide.Keywords
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