Bicycloprop‐2‐enyl (C6H6)
Authors:
- 1 December 1989
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 101 (12) , 1735-1737
Abstract
Das einzige Valenzisomer von Benzol, dessen Synthese bislang noch ausstand, wurde durch Reaktion des β‐Halogensilans 1 mit Tetra‐n‐butylammoniumfluorid im Vakuum erhalten und 1H‐NMR‐spektroskopisch charakterisiert. Bicycloprop‐2‐enyl 2 kann mit Cyclopentadien als Diels‐Alder‐Addukt abgefangen werden. In Gegenwart von Ag⊕ lagert es in Dewar‐Benzol um. magnified imageKeywords
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