Synthesis of Biaryls Using the Coupling Reaction of Diaryldimethyltins with Copper(II) Nitrate

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Abstract
The coupling of diaryldimethyltins with Cu(NO3)2·3H2O in THF proceeds smoothly at room temperature under ambient atmosphere to produce the corresponding biaryls in good to high yields. Diaryldimethyltins can be prepared in high yields by the reaction of aryllithiums with dichlorodimethyltin.

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