Oscillators Perturbed by Gaussian Barriers
Authors:
- 1 August 1963
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 39 (3) , 545-551
Abstract
A simple method has been developed to generate the matrix elements of the operator exp (—βξ2) in the representation of the harmonic oscillator. These matrix elements are useful in double-minimum problems where the potential energy function may conveniently be represented by a perturbed harmonic oscillator with a Gaussian barrier. Some representative calculations involving such potential wells will also be presented.Keywords
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