Dendrimers and hyper-branched polymers interacting with clays: fruitful associations for functional materials
- 31 July 2019
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry A
- Vol. 7 (34) , 19634-19650
Abstract
The possibility to incorporate diverse chemical species inside clays, especially swelling clay minerals, has been known for more than two millennia, but the first examples of man-made polymers interacting with clays only date back to about 30 years ago. Dendrimers and hyper-branched polymers differ from classical polymers by their intrinsically 3-dimensional structure, and by their large number of reactive functional groups. The study of their interaction with clays/clay minerals is relatively recent. Besides the fundamental research done on these kinds of organoclays, different potential uses have already been investigated. In this review, we will present an overview of the studies dealing with the synthetic processes, and the characterization of the resulting dendrimer/hyper-branched polymer–clay mineral (nano)composites. Special attention will be focussed on the properties of these new hybrid smart materials, in different fields ranging from catalysis, trapping gases (in particular CO2 and H2), energy conversion and storage, flame retardants, and biology (biosensors, hydrogels, and drug delivery) to water treatment (wastewater and water-based drilling fluids).Keywords
Funding Information
- Centre National de la Recherche Scientifique (no number)
This publication has 138 references indexed in Scilit:
- OH-enriched organo-montmorillonites for potential applications in carbon dioxide separation and concentrationSeparation and Purification Technology, 2013
- Organo and inorgano-organo-modified clays in the remediation of aqueous solutions: An overviewApplied Clay Science, 2012
- Recent Advances in Clay/Polymer NanocompositesAdvanced Materials, 2011
- Chromium in Drinking Water: Sources, Metabolism, and Cancer RisksChemical Research in Toxicology, 2011
- TPD study of the reversible retention of carbon dioxide over montmorillonite intercalated with polyol dendrimersThermochimica Acta, 2009
- Synthesis and characterization of hyperbranched poly(amine-ester)/lanthanum/montmorillonite nanocompositesMaterials Letters, 2008
- Correlating the rheological and mechanical response of polyurethane nanocomposites containing hyperbranched polymersPolymer, 2005
- Hyperbranched polymer/montmorillonite clay nanocompositesPolymer, 2004
- Nanocomposites based on a combination of epoxy resin, hyperbranched epoxy and a layered silicatePolymer, 2003
- Effect of polymer architecture on the miscibility of polymer/clay mixturesPolymer International, 2000