Nucleation-Limited Dewetting of Ice Films on Pt(111)

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Abstract
Quantifying dewetting phenomena at the microscopic level is the key to deciphering how a balance between kinetic and equilibrium effects determines ice-film morphology on Pt(111). Overcoming the difficulty of imaging nominally insulating ice multilayers with scanning tunneling microscopy allowed us to track the dewetting process. The results show that the rate at which new layers nucleate, and not surface diffusion, determines how fast individual crystallite shapes equilibrate. Applying nucleation theory to measured growth rates versus crystallite size, we obtain new bounds on the energetics both of step formation on ice and of the Pt-ice interface.