Rhodium-Catalyzed One-Pot Synthesis of Substituted Pyridine Derivatives from α,β-Unsaturated Ketoximes and Alkynes
- 20 December 2007
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 10 (2) , 325-328
Abstract
A rhodium-catalyzed chelation-assisted C−H activation of α,β-unsaturated ketoximes and the reaction with alkynes to afford highly substituted pyridine derivatives is described.Keywords
This publication has 39 references indexed in Scilit:
- Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct ArylationChemical Reviews, 2007
- sp3 C−H Bond Arylation Directed by Amidine Protecting Group: α-Arylation of Pyrrolidines and PiperidinesJournal of the American Chemical Society, 2006
- Direct C−H Arylation of (Hetero)arenes with Aryl Iodides via Rhodium CatalysisJournal of the American Chemical Society, 2006
- C-H Bond Functionalization in Complex Organic SynthesisScience, 2006
- Catalytic Methods for C-H Bond Functionalization: Application in Organic SynthesisAdvanced Synthesis & Catalysis, 2003
- Transition Metal Reagents and Catalysts2002
- Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic AspectsChemical Reviews, 2002
- Transition Metal Catalyzed Coupling Reactions under C−H ActivationAngewandte Chemie International Edition, 1999
- Transition Metal-Catalyzed Carbocyclizations in Organic SynthesisChemical Reviews, 1996
- Transition Metal-Mediated Cycloaddition ReactionsChemical Reviews, 1996