Crystallization Features of MAPbI3 Hybrid Perovskite during the Reaction of PbI2 with Reactive Polyiodide Melts
Authors:
- 19 February 2021
- journal article
- research article
- Published by Pleiades Publishing Ltd in Russian Journal of Inorganic Chemistry
- Vol. 66 (2) , 153-162
Abstract
The formation stages of hybrid halide perovskite MAPbI3 when methylammonium-based reactive polyiodide melts (RPMs) are reacted with PbI2 platy crystals at room temperature are studied. The local dissolution of the lead-containing precursor and subsequent crystallization of homogeneously formed nuclei is found to be the major perovskite crystallization mechanism under these conditions. The iodine content in the reaction mixture acts as a very important parameter for controlling the rate and degree of PbI2 conversion, which can be used to develop new preparation techniques to produce light-harvesting layers for solar cells with a tunable coating morphology.Keywords
This publication has 34 references indexed in Scilit:
- Challenges for commercializing perovskite solar cellsScience, 2018
- Solar photovoltaics: current state and trendsPhysics-Uspekhi, 2016
- Defect Tolerance in Methylammonium Lead Triiodide PerovskiteACS Energy Letters, 2016
- Chalcogenide perovskites – an emerging class of ionic semiconductorsNano Energy, 2016
- Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cellsNature Materials, 2014
- Homogeneous Emission Line Broadening in the Organo Lead Halide Perovskite CH3NH3PbI3–xClxThe Journal of Physical Chemistry Letters, 2014
- Band-gap tuning of lead halide perovskites using a sequential deposition processJournal of Materials Chemistry A, 2014
- Perovskite as Light Harvester: A Game Changer in PhotovoltaicsAngewandte Chemie International Edition, 2014
- Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite AbsorberScience, 2013
- Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3Science, 2013