Observation of three different linker conformers in a scandium ferrocenedicarboxylate coordination polymer
- 12 August 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 22 (34) , 5569-5572
Abstract
Electron and powder diffraction were combined to elucidate the structure of the new coordination polymer [Sc2(FcDC)3] based on 1,1′-ferrocenedicarboxylate (FcDC2−), denoted as CAU-50. Remarkably, three different conformers of the very same linker molecule are observed, two of which serve as connectors for the scandium cations while one conformer acts as capping agent.Keywords
Funding Information
- Deutsche Forschungsgemeinschaft (RE 4057/1-1)
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