Hyperfine Structure in the Microwave Spectrum of Water. II. Effects of Magnetic Interactions

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  • DPDw Posener
    Dw Posener
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Abstract
Further analysis of the hyperfine structure appearing in the observed microwave spectra of HDO and D.O, taking into account nuclear quadrupole and magnetic dipole interactions, leads to a complete determination of the electric field gradient tensor at the hydrogen nuclei in the water molecule, giving a value along the bond direction of (+ 1· 59 ±O· 04) X 1015 e.s.u.