Cenomanian to Coniacian Water-mass Evolution in the Cretaceous Western Interior Seaway of North America and Equatorial Atlantic

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Abstract
The Late Cretaceous Epoch was characterized major global perturbations in the carbon cycle, the most prominent occurring near the Cenomanian-Turonian (CT) transition marked by Oceanic Anoxic Event/OAE-2 at 94.9–93.7 Ma. The Cretaceous Western Interior Seaway (KWIS) was one of several epicontinental seas in which a complex water-mass evolution was recorded in widespread sedimentary successions. This contribution integrates new data on the main components of organic matter, geochemistry, and stable isotopes along a North-South transect from the KWIS to the equatorial western Atlantic and Southern Ocean. In particular, cored sedimentary rocks from the Eagle Ford Group of West Texas (~ 90–98 Ma) demonstrate subtle temporal and spatial variations in paleoenvironmental conditions and provide an important geographic constraint for interpreting water-mass evolution. High latitude (boreal-austral), equatorial tethyan and locally sourced Western Interior Seaway water-masses are distinguished by distinct palynological assemblages and geochemical signatures. The northward migration of a tethyan water-mass into the KWIS occurred during the early-middle Cenomanian (98–95 Ma) followed by a major re-organization during the latest Cenomanian-Turonian (95–94 Ma) as a full connection with a northerly- boreal water-mass was established during peak transgression. This oceanographic change promoted de-stratification of the water column and improved oxygenation throughout the KWIS and as far south as the Demerara Rise off Suriname. In addition the recorded decline in redox-sensitive trace metals during the onset of OAE-2 likely reflects a genuine oxygenation event related to open water-mass exchange and may have been complicated by variable contribution of organic matter from different sources (e.g. refractory/terrigenous material), requiring further investigation.
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