Deep near-infrared emission from a dinuclear platinum(diimine)(dithiolene) complex
Open Access
- 14 October 2026
- journal article
- Published by Royal Society of Chemistry (RSC) in Inorganic Chemistry Frontiers
- Vol. 13 (20) , 8676-8686
Abstract
A benzenetetrathiolate-bridged dinuclear platinum(diimine)(dithiolene) complex exhibits unprecedented deep near-infrared luminescence (1172 nm) upon two-electron oxidation.Keywords
Funding Information
- Agence Nationale de la Recherche (19-CE08-0029-02)
- Army Research Office (W911NF-23-1-0233)
- National Science Foundation (CHE-2155082)
- U.S. Department of Energy (DE-AC02-06CH11357)
This publication has 38 references indexed in Scilit:
- A Bimetallic Benzene‐1,2,4,5‐Tetrathiolate (btt) Molybdenocene Complex Cp2Mo(btt)MoCp2: Radical and Diradical StatesChemistry – A European Journal, 2023
- Heteroatom substitution for the development of near-IR lumiphoresTrends in Chemistry, 2022
- Thiosemiquinoid Radical-Bridged CrIII2 Complexes with Strong Magnetic Exchange CouplingInorganic Chemistry, 2019
- Redox-Active Metallodithiolene Groups Separated by Insulating Tetraphosphinobenzene SpacersInorganic Chemistry, 2018
- Multielectron‐Transfer Templates via Consecutive Two‐Electron Transformations: Iron–Sulfur Complexes Relevant to Biological EnzymesChemistry – A European Journal, 2012
- Structure–Property Relationships in Pt II Diimine‐Dithiolate Nonlinear Optical Chromophores Based on Arylethylene‐1,2‐dithiolate and 2‐Thioxothiazoline‐4,5‐dithiolateEuropean Journal of Inorganic Chemistry, 2012
- A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh)2Mo(μ‐CO)2(CO)}2(S2C6H2S2)2] with Two π‐Conjugated S2C6S2 Bridges: Synthesis, Crystal Structure, and PropertiesAngewandte Chemie International Edition, 2009
- Platinum diimine complexes: towards a molecular photochemical deviceCoordination Chemistry Reviews, 2000
- Luminescent platinum complexes: tuning and using the excited stateCoordination Chemistry Reviews, 1998
- Platinum(II) diimine dithiolates. New solution luminescent complexesCoordination Chemistry Reviews, 1990