A Novel Open‐Framework Cobalt Phosphate Containing a Tetrahedrally Coordinated Cobalt(II) Center: CoPO4 · 0.5 C2H10N2
Authors:
- Jiesheng ChenJCJiesheng Chen
- Srinivasan NatarajanSNSrinivasan Natarajan
- John Meurig ThomasJTJohn Meurig Thomas
- Richard H. JonesRJRichard H. Jones
- 31 March 1994
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 33 (6) , 639-640
Abstract
A network of alternating CoO4 and PO4 tetrahedra linked through corners is formed by the blue title compound. The CoII centers are exclusively in a tetrahedral environment, as the compound's color indicates. The channels, whose pore openings (with respect to Co and P atoms only) are regular octahedra in one direction, but compressed eight‐membered rings in the others, lie parallel to the crystallographic axes.Keywords
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